So, I started trying to find out what the scanner was and some kind of pinout for the odd serial connector. The scanner is a Datalogic Touch65 Light Wedge RS232. The fact it had RS232 in it's name gave me hope that somewhere in the mix was a standard RS232 interface. I started searching for some kind of description of the cable I had, but kept finding that the unit can have several different types of cable. This led me on to search for pinouts of the different cables.
A few minutes later, Google turns up this result:
http://www.dhtechnology.com.au/pdfs/barcode%20scanners/Standard%20cable%20diagrams.pdf
This lists pinouts for all the cables. After some looking at the serial end, I found that I have "power on pin 9" style cable. So from here I could wire up a serial connection. The only problem now is that I don't have any serial ports on my computer!
A quick look at ebay and I find a genuine prolific PL2303 USB to serial adapter for less than a fiver. Bargain.
Once it arrived, I just had to wire it all up and get a 5v source (USB is great for this), and it worked first time!

I'm using AACKeys to convert the scanned codes into keystrokes, but it's working fine. Now, back to my audit... :)